SPARTAN EP 320
EXXON COMPANY, U.S.A
DATE ISSUED: 03/22/99
SUPERSEDES DATE: 01/24/97
MATERIAL SAFETY DATA SHEET
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SECTION 1: PRODUCT AND COMPANY IDENTIFICATION
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COMPANY: EXXON COMPANY, U.S.A.
P.O. BOX 2180
HOUSTON, TX 77252-2180
PRODUCT NAME PRODUCT CODE
SPARTAN EP 320 475384
PRODUCT CATEGORY
Petroleum Lubricating Oil
MEDICAL EMERGENCY TELEPHONE NUMBER: (713) 656-3424
TRANSPORTATION EMERGENCY TELEPHONE NUMBERS
(BAYTOWN) (281) 834-3296 (CHEMTREC) 1-800-424-9300
Product Information and Technical Assistance: 1-800-443-9966
FAXED MSDSs: 1-800-298-4007 MAILED MSDSs OR OTHER ASSISTANCE: (713) 656-5949
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SECTION 2: COMPOSITION/INFORMATION ON INGREDIENTS
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CAS NO. OF APPROXIMATE
COMPONENTS COMPONENTS CONCENTRATION
Distillates (petroleum), hydrotreated 64742-54-7 Approximately 98%
heavy paraffinic
or or
Distillates (petroleum), solvent- 64742-65-0
dewaxed heavy paraffinic
and and
Residual oils (petroleum), hydrotreated 64742-57-0
or or
Residual oils (petroleum), solvent- 64742-62-7
dewaxed
Proprietary additives Mixture Approximately 2%
SEE SECTION 8 FOR EXPOSURE LIMITS
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SECTION 3: HAZARDS IDENTIFICATION
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EMERGENCY OVERVIEW
OSHA REQUIRED LABEL INFORMATION
In compliance with hazard and right-to-know requirements, where applicable
OSHA Hazard Warnings may be found on the label, bill of lading or invoice
accompanying this shipment.
Note: Product label may contain non-OSHA related information also.
HAZARDOUS MATERIALS IDENTIFICATION SYSTEM (HMIS)
Health Flammability Reactivity BASIS
1 1 0 Recommended by Exxon
NATIONAL FIRE PROTECTION ASSOCIATION (NFPA) - HAZARD IDENTIFICATION
Health Flammability Reactivity BASIS
1 1 0 Recommended by Exxon
VARIABILITY AMONG INDIVIDUALS
Health studies have shown that many petroleum hydrocarbons and synthetic
lubricants pose potential human health risks which may vary from person to
person. As a precaution, exposure to liquids, vapors, mists or fumes should
be minimized.
EFFECTS OF OVEREXPOSURE (Signs and symptoms of exposure)
Prolonged or repeated skin contact may cause skin irritation.
PRE-EXISTING MEDICAL CONDITIONS WHICH MAY BE AGGRAVATED BY EXPOSURE
None recognized
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SECTION 4: FIRST AID MEASURES
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EYE CONTACT
If splashed into the eyes, flush with clear water for 15 minutes or until
irritation subsides. If irritation persists, call a physician.
SKIN
In case of skin contact, remove any contaminated clothing and wash skin with
soap and water. Launder or dry-clean clothing before reuse. If product is
injected into or under the skin, or into any part of the body, regardless of
the appearance of the wound or its size, the individual should be evaluated
immediately by a physician as a surgical emergency. Even though initial
symptoms from high pressure injection may be minimal or absent, early surgical
treatment within the first few hours may significantly reduce the ultimate
extent of injury.
INHALATION
Vapor pressure is very low. Vapor inhalation under ambient conditions is
normally not a problem. If overcome by vapor from hot product, immediately
remove from exposure and call a physician. If breathing is irregular or has
stopped, start resuscitation; administer oxygen, if available. If overexposed
to oil mist, remove from further exposure until excessive oil mist condition
subsides.
INGESTION
If ingested, DO NOT induce vomiting; call a physician immediately.
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SECTION 5: FIRE-FIGHTING MEASURES
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FLASH POINT (MINIMUM) AUTOIGNITION TEMPERATURE
Greater than 204~C (399~F) Greater than 260~C (500~F)
ASTM D 92, Cleveland Open Cup
FLAMMABLE OR EXPLOSIVE LIMITS (APPROXIMATE PERCENT BY VOLUME IN AIR)
Estimated values: Lower Flammable Limit 0.9% Upper Flammable Limit 7%
EXTINGUISHING MEDIA AND FIRE FIGHTING PROCEDURES
Foam, water spray (fog), dry chemical, carbon dioxide and vaporizing liquid
type extinguishing agents may all be suitable for extinguishing fires
involving this type of product, depending on size or potential size of fire
and circumstances related to the situation. Plan fire protection and response
strategy through consultation with local fire protection authorities or
appropriate specialists.
The following procedures for this type of product are based on the
recommendations in the National Fire Protection Association's "Fire Protection
Guide on Hazardous Materials", Tenth Edition (1991):
Use water spray, dry chemical, foam or carbon dioxide to extinguish the fire.
Use water to keep fire-exposed containers cool. If a leak or spill has not
ignited, use water spray to disperse the vapors and to provide protection for
persons attempting to stop a leak. Water spray may be used to flush spills
away from exposures. Minimize breathing of gases, vapor, fumes or
decomposition products. Use supplied-air breathing equipment for enclosed or
confined spaces or as otherwise needed.
DECOMPOSITION PRODUCTS UNDER FIRE CONDITIONS
Fumes, smoke, carbon monoxide, sulfur oxides, phosphorus oxides, nitrogen
oxides, metal oxides, aldehydes and other decomposition products, in the case
of incomplete combustion.
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SECTION 6: ACCIDENTAL RELEASE MEASURES
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CLEAN WATER ACT / OIL POLLUTION ACT
This product may be classified as an oil under Section 311 of the Clean Water
Act, and under the Oil Pollution Act. Discharges or spills into or leading to
surface waters that cause a sheen must be reported to the National Response
Center (1-800-424-8802).
STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED
Recover free product. Add sand, earth or other suitable absorbent to spill
area. Minimize breathing vapors. Minimize skin contact. Open all windows
and doors. Keep product out of sewers and watercourses by diking or
impounding. Advise authorities if product has entered or may enter sewers,
watercourses, or extensive land areas.
Assure conformity with applicable governmental regulations.
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SECTION 7: STORAGE AND HANDLING
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HANDLING PRECAUTIONS
Use product with caution around heat, sparks, pilot lights, static
electricity, and open flame.
"EMPTY" CONTAINER WARNING
"Empty" containers retain residue (liquid and/or vapor) and can be dangerous.
DO NOT PRESSURIZE, CUT, WELD, BRAZE, SOLDER, DRILL, GRIND OR EXPOSE SUCH
CONTAINERS TO HEAT, FLAME, SPARKS, STATIC ELECTRICITY, OR OTHER SOURCES OF
IGNITION; THEY MAY EXPLODE AND CAUSE INJURY OR DEATH.
Do not attempt to refill or clean containers since residue is difficult to
remove. "Empty" drums should be completely drained, properly bunged and
promptly returned to a drum reconditioner. All other containers should be
disposed of in an environmentally safe manner and in accordance with
governmental regulations.
For work on tanks refer to Occupational Safety and Health Administration
regulations, ANSI Z49.1, and other governmental and industrial references
pertaining to cleaning, repairing, welding, or other contemplated operations.
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SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION
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EXPOSURE LIMIT FOR TOTAL PRODUCT BASIS
5 mg/m3 for oil mist (aerosol) for OSHA Regulation 29 CFR 1910.1000 and
an 8-hour workday recommended by the American Conference
of Governmental Industrial Hygienists
(ACGIH). ACGIH states that the air is
to be sampled by a method that does not
collect vapor; in addition, it lists a
10 mg/m3 STEL.
VENTILATION
Use local exhaust to capture vapor, mists or fumes, if necessary. Provide
ventilation sufficient to prevent exceeding recommended exposure limit or
buildup of explosive concentrations of vapor in air. No smoking, or use of
flame or other ignition sources.
RESPIRATORY PROTECTION
Use supplied-air respiratory protection in confined or enclosed spaces, if
needed.
PROTECTIVE GLOVES
Use chemical-resistant gloves, if needed, to avoid prolonged or repeated skin
contact.
EYE PROTECTION
Use splash goggles or face shield when eye contact may occur.
OTHER PROTECTIVE EQUIPMENT
Use chemical-resistant apron or other impervious clothing, if needed, to avoid
contaminating regular clothing, which could result in prolonged or repeated
skin contact.
WORK PRACTICES / ENGINEERING CONTROLS
To prevent fire or explosion risk from static accumulation and discharge,
effectively bond and/or ground product transfer system in accordance with
(THE) National Fire Protection Association PUBLICATIONS.
Keep containers closed when not in use. Do not store near heat, sparks, flame
or strong oxidants.
In order to prevent fire or explosion hazards, use appropriate equipment.
Information on electrical equipment appropriate for use with this product may
be found in the latest edition of the National Electrical Code (NFPA-70).
This document is available from the National Fire Protection Association,
Batterymarch Park, Quincy, Massachusetts 02269.
PERSONAL HYGIENE
Minimize breathing vapor, mist or fumes. Avoid prolonged or repeated contact
with skin. Remove contaminated clothing; launder or dry-clean before re-use.
Remove contaminated shoes and thoroughly clean before re-use; discard if
oil-soaked. Cleanse skin thoroughly after contact, before breaks and meals,
and at end of work period. Product is readily removed from skin by waterless
hand cleaners followed by washing thoroughly with soap and water.
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SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES
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The following data are approximate or typical values and should not be used
for precise design purposes.
BOILING RANGE VAPOR PRESSURE
IBP Approximately 371~C (700~F) Less than 0.01 mm Hg @ 20~C
SPECIFIC GRAVITY (15.6~C/15.6~C) VAPOR DENSITY (AIR = 1)
0.91 Greater than 5
MOLECULAR WEIGHT PERCENT VOLATILE BY VOLUME
Not determined Negligible from open container
in 4 hours @ 38~C (100~F)
EVAPORATION RATE @ 1 ATM. AND 25~C
pH (77~F) (n-BUTYL ACETATE = 1)
Essentially neutral Less than 0.01
SOLUBILITY IN WATER @ 1 ATM.
POUR, CONGEALING OR MELTING POINT AND 25~C (77~F)
-15~C (5~F) Negligible; less than 0.1%
Pour Point by ASTM D 97
VISCOSITY
320 cSt @ 40~C
PRODUCT APPEARANCE AND ODOR
Clear, light brown liquid
Mild, bland odor
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SECTION 10: STABILITY AND REACTIVITY
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This product is stable and will not react violently with water. Hazardous
polymerization will not occur. Avoid contact with strong oxidants such as
liquid chlorine, concentrated oxygen, sodium hypochlorite, calcium
hypochlorite, etc., as this presents a serious explosion hazard.
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SECTION 11: TOXICOLOGICAL INFORMATION
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NATURE OF HAZARD AND TOXICITY INFORMATION
Repeated and prolonged overexposure to oil mists may result in droplet
deposition, oil granuloma formation, inflammation and increased incidence of
infection.
In accordance with the current OSHA Hazard Communication Standard criteria,
this product does not require a cancer hazard warning. This is because the
product is formulated from base stocks which are severely hydrotreated,
severely solvent extracted, and/or processed by mild hydrotreatment and
extraction. Alternatively, it may consist of components not otherwise
affected by IARC criteria, such as atmospheric distillates or synthetically
derived materials, and as such is not characterized by current IARC
classification criteria.
Prolonged or repeated skin contact with this product tends to remove skin
oils, possibly leading to irritation and dermatitis; however, based on human
experience and available toxicological data, this product is judged to be
neither a "corrosive" nor an "irritant" by OSHA criteria.
Product contacting the eyes may cause eye irritation.
Product has a low order of acute oral and dermal toxicity, but minute amounts
aspirated into the lungs during ingestion or vomiting may cause mild to severe
pulmonary injury and possibly death.
This product is judged to have an acute oral LD50 (rat) greater than 5 g/kg of
body weight, and an acute dermal LD50 (rabbit) greater than 3.16 g/kg of body
weight.
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SECTION 12: ECOLOGICAL INFORMATION
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Do not discharge this product into public waters or waterways unless
authorized by a National Pollution Discharge Elimination System (NPDES) permit
issued by the Environmental Protection Agency (EPA).
Environmental and Ecological data may be available for this product. Write or
call Exxon to obtain further information. Refer to Section 6 and Section 15
for Accidental Release information and Regulatory Reporting information.
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SECTION 13: DISPOSAL CONSIDERATION
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Options for disposal of this product may depend on the conditions under which
it was used. To determine the proper method of disposal, refer to RCRA (40
CFR 261), as well as federal EPA and state and local regulations.
Please refer to Sections 5, 6 and 15 for additional information.
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SECTION 14: TRANSPORTATION INFORMATION
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TRANSPORTATION INCIDENT INFORMATION
For further information relative to spills resulting from transportation
incidents, refer to latest Department of Transportation Emergency Response
Guidebook for Hazardous Materials Incidents.
U.S. DOT HAZARDOUS MATERIALS SHIPPING DESCRIPTION
Not regulated
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SECTION 15: REGULATORY INFORMATION
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U.S. FEDERAL REGULATIONS
THE FOLLOWING INFORMATION MAY BE USEFUL IN COMPLYING WITH VARIOUS STATE AND
FEDERAL LAWS AND REGULATIONS UNDER VARIOUS ENVIRONMENTAL STATUTES:
THRESHOLD PLANNING QUANTITY (TPQ), EPA REGULATION 40 CFR 355
(SARA Sections 301-304)
No TPQ for product or any constituent greater than 1% or 0.1% (carcinogen).
TOXIC CHEMICAL RELEASE REPORTING, EPA REGULATION 40 CFR 372 (SARA Section 313)
No toxic chemical is present greater than 1% or 0.1% (carcinogen).
HAZARDOUS CHEMICAL REPORTING, EPA REGULATION 40 CFR 370 (SARA Sections 311-312)
EPA Hazard Classification Code: Not Applicable
TOXIC SUBSTANCES CONTROL ACT (TSCA)
This product contains the following TSCA 12b reportable chemical substance(s):
Isopropanol (IPA) CAS # 67-63-0
This product, as manufactured by Exxon, does not contain polychlorinated
biphenyls (PCB's).
All components of this product are listed on the U.S. TSCA inventory.
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SECTION 16: OTHER INFORMATION
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The health and safety information presented herein must be used in conjunction
with the pertinent standards for training, work practices and facilities
design established by OSHA, NIOSH, NFPA, API, NEC, NSC, UNDERWRITERS, BUREAU
OF MINES, and similar organizations.
The information and recommendations contained herein are, to the best of
Exxon's knowledge and belief, accurate and reliable as of the date issued.
Exxon does not warrant or guarantee their accuracy or reliability, and Exxon
shall not be liable for any loss or damage arising out of the use thereof.
The information and recommendations are offered for the user's consideration
and examination, and it is the user's responsibility to satisfy itself that
they are suitable and complete for its particular use. If buyer repackages
this product, legal counsel should be consulted to insure proper health, safety
and other necessary information is included on the container.
The Environmental Information included under Section 15 hereof as well as the
Hazardous Materials Identification System (HMIS) and National Fire Protection
Association (NFPA) ratings have been included by Exxon Company, U.S.A. in order
to provide additional health and hazard classification information. The ratings
recommended are based upon the criteria supplied by the developers of these
rating systems, together with Exxon's interpretation of the available data.